Question:
I
am very new to the vacuum-furnace world and work for a company that sinters
stainless mesh in a single-chamber vacuum furnace. In our process, we will
generally run several jobs in a load (all stainless). My questions relate to
the method we use to separate the mesh. We use a ceramic paper, which becomes “dirty”
after repeated use. In fact, when I change my diffusion pump oil it is caked
with the fibers from this material. I have also seen some instances where it
seems the paper itself becomes bonded to the mesh and becomes very difficult to
remove. I was wondering if you might be able to recommend a different way or
product to help eliminate or reduce these issues.
Answer:
Ceramic paper is used by a number of companies in the industry in their
vacuum furnaces to prevent parts from sticking together. It is relatively
inexpensive, easy to use and is (in general) effective for its intended
purpose. However, it has quite a number of detrimental features: it affects
(lengthens) pump-down times since it is hydroscopic (i.e. absorbs moisture as
it sits around outside the furnace and subsequently releases that moisture
during initial pump-down and heat-up); it is easily mechanically damaged; it
becomes more and more brittle after first and subsequent uses, allowing
fibers to be released (as you have found); and it absorbs all sorts of contaminants (carbon-bearing and other) such as oils, dirt, etc. This explains why, in your case,
the paper becomes bonded to the stainless steel. In your application, I
would recommend that the paper be discarded either after each use or
after just a few uses (before it becomes dark).
There are a number of substitute materials and methods that you may find
better in your application but, once again, each has pros and cons. As far as
ceramic-fiber materials go, you might wish to check out a product from Thermal
Ceramics called K-Shield BF paper. This is used by a number of commercial heat
treaters. It has an organic-free binder, which is a plus (many data sheets
like the one you sent do not list the binder type). Commercial heat treaters
I’ve talked with recommend a 1/32-inch (0.8 mm) paper and only a one-time
usage before you throw it away. If bought in bulk, it must be stored in such a
way as to prevent moisture pickup. There are also a number of spray powders on
the market, the two most popular being boron nitride and aluminum-oxide
powders. You might also consider using a vacuum brazing stop-off compound
painted on the surface of a separator screen (it must be thoroughly dry). Be
aware that many of these products go on one color and turn another color after
use, which might affect the brightness/color of the stainless. Wall Colmonoy
makes a green (as I recall) brazing stop-off that comes out black after use, and
the boron-nitride spray goes on white and comes out a grayish white.
Use of Ceramic Paper in Vacuum Furnaces

Dan Herring is president of THE HERRING GROUP Inc., which specializes in consulting services (heat treatment and metallurgy) and technical services (industrial education/training and process/equipment assistance). He is also a research associate professor at the Illinois Institute of Technology/Thermal Processing Technology Center. tel: 630-834-3017; e-mail: dherring@heat-treat-doctor.com; web: www.heat-treat-doctor.com
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